摘要:采用ABR-SBR工艺处理生活污水,考察了影响反应器处理效果的因素和工艺对污染物的去除效果。结果表明:在ABR水力停留时间为12h,SBR厌氧时间为2h、曝气时间为3.5h的情况下,ABR-SBR工艺处理生活污水,出水COD和SS达到城镇污水处理厂污染物排放标准(GB118-2002)中一级A标准,出水的氨氮、TN和TP均优于GB118-2002的一级B标准。
关键词:ABR反应器;SBR反应器;生活污水
中图分类号:X703 文献标识码:A 文章编号:1007-2284(2012)02-0075-03
ABR反应器是在UASB反应器的基础上发展起来的,具有运行方式简单、管理方便、经济投入低及对生物量具有优良的截留能力和运行性能可靠等优点[1,2]。采用ABR反应器对生活污水进行处理,使污水中大部分有机物得到降解,但是对氮和磷的去除效果较差,难以达到越来越严格的排放标准。为了脱氮除磷并进一步去除有机物,笔者采用SBR作为后续处理,确定了最佳运行参数和对生活污水的处理效果。
1 试验装置与方法
1.1 试验装置
ABR反应器和SBR装置均采用有机玻璃加工制作。ABR反应器由3个隔室组成,有效容积为30L,反应器上流室和下流室的水平宽度比为3∶1。设计折流板底部折角为45°,这样可以使底物和生物量更好的接触[3,4]。进水采用蠕动泵加压,产生的沼气由反应器顶部排出。SBR反应器有效容积为20L,工艺流程如图1所示。
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance the sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks
图1 工艺流程
1.2 原水水质
试验原水为河北工程大学校内生活污水,水质指标见表1。
表1 原水水质 mg/L
1.3 分析项目及方法
COD:重铬酸钾法;SS:重量法;氨氮:纳氏试剂分光光度法;TP:钼酸铵分光光度法;TN:过硫酸钾氧化-紫外分光光度法[5]。
2 结果与讨论
2.1 ABR反应器处理效果的影响因素
2.1.1 水力停留时间对处理效果的影响
通过改变进水流量来调节水力停留时间,当水力停留时间分别为36、30、24、20、15、12、10、8、6h时,系统对有机物的去除效果如图2所示。
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance he sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks
图2 水力停留时间对COD去除效果的影响
从图2可见,在HRT由30h缩短至12h过程中,对COD去除率和COD出水浓度影响不大;当HRT降至10h以下时,对COD去除率和COD出水浓度开始下降,因为停留时间太短,微生物完成对有机物的有效降解时间达不到;但当HRT为36h时,出水水质较差,主要原因是水力停留时间太长,上升流速超出一定范围后,反应器中的污泥可能会被过大的水力冲击作用而带出反应器,使得反应器内不能保持足够多的生物量,从而影响去除效果。在实际工程运用中,当反应器的容积已经确定,水力停留时间越小,单位时间处理的废水量越大,因此选择水力停留时间(HRT)的参数为12h,且在该参数条件下出水COD均小于100mg/L,且COD去除效果良好。
2.1.2 温度对处理效果的影响
固定HTR为12h,研究在不同温度下ABR反应器对COD的去除效果,如表2所示。
从表2可以看出,随着水温的升高,COD去除率随之增加,温度的升高可以加快厌氧消化菌对有机污染物的分解速率,并能降低厌氧污泥混合液的黏度,这使污泥的沉降性能发生了变化,从而影响了出水的水质。温度大于16.0℃,COD去除效率大于70%,出水
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance the sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacksCOD小于100mg/L;当水温小于13℃时COD出水大于100mg/L,但是仍有50%的去除率,是因为系统内保持了最大的生物量,在一定程度上抵消了温度下降所带来的不利影响。说明反应器在短HRT及中低温下处理生活污水是可行的,但在北方冬季当水温过低时可采取一定的措施提高COD的去除率,如:延长HRT、增加外循环或对反应器进行保温等。
表2 温度对COD去除效果的影响
2.1.3 容积负荷对处理效果的影响
在厌氧生物处理中,容积负荷是一个重要的工艺参数,它集中反映了进水浓度和水力停留时间对厌氧生物处理过程的综合影响。进水容积负荷与COD去除率之间的关系见图3。
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance he sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks
图3 容积负荷对COD去除效果的影响
从图3中可看出,进水容积负荷在0.37~1.042kg/(m3·d)变化,随着容积负荷的增加,COD去除率逐渐增加,当容积负荷增加到0.69kg/(m3·d)时,COD去除率增加到80%,继续增加容积负荷COD的去除率变化不大,都在80%以上。说明当容积负荷在0.69~1.042kg/(m3·d)时,ABR厌氧反应系统对容积负荷的冲击具有较好的适应性。
2.2 SBR反应器处理效果的影响因素
2.2.1 厌氧时间对处理效果的影响
厌氧时间是影响磷去除效果的重要因素。磷的去除是通过聚磷菌在厌氧时释磷,在好氧时过量吸磷来实现的。磷的厌氧释放是好氧吸磷和除磷的前提条件,吸磷能力的大小取决于磷的厌氧释放情况。厌氧释磷越充分,聚磷菌贮存的能量就越多,到了好氧阶段吸磷效果就越好,出水的磷浓度就越低,处理效果就越好。污水中总磷浓度随时间的变化趋势见图4。
从图4可以看出,厌氧2h聚磷菌放磷基本完毕,总磷浓度从6.12升至10.34mg/L。若再增加厌氧时间,放磷速度相当缓慢,因此确定厌氧时间为2h。
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance the sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks
图4 厌氧时间对TP去除效果的影响
2.2.2 曝气时间对处理效果的影响
曝气时间是影响处理效果最主要的因素。污水中COD和氨氮浓度随时间的变化趋势见图5和图6。
图5 曝气时间对COD去除效果的影响
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance he sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks 图6 曝气时间对氨氮去除效果的影响
从图5可以看出,在曝气1h后COD降到50mg/L,已经能够满足城镇污水处理厂污染物排放标准(GB118-2002)中一级A标准;曝气2h后COD降到25.7mg/L;继续增加曝气时间对COD的去除效果基本不再增加。事实上由于ABR工艺已去除大部分的有机物,所以SBR在较短的时间内出水的COD就能达到排放的标准。从图6可以看出,曝气1h,氨氮从23.5mg/L降低到19.7mg/L,去除率只有16.2%;当曝气时间在3.5h以上时,氨氮浓度小于5.5mg/L。综合曝气时间对COD和氨氮去除效果的影响,确定曝气时间为3.5h。
以前面确定的最佳厌氧、曝气时间确定SBR的运行周期为10h,进水2h,曝气3.5h,停曝搅拌2h,沉淀1h,排水0.5h,静置1h。
2.3 ABR-SBR对生活污水的处理效果
ABR-SBR工艺对生活污水的处理效果见表3。
表3 对生活污水的处理效果mg/L
从表3可以看出,ABR反应器对COD处理效果较好,出水COD<100mg/L,对SS也有一定的去除,去除率在70%以上;但是对氮、磷的处理效果较差,有时出水的氨氮和磷比进水的还高。采用SBR进行后续处理,出水COD和SS达到城镇污水处理厂污
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance the sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks染物排放标准(GB118-2002)中一级A标准;出水的氨氮、TN和TP优于GB118-2002的一级B标准。
3 结 论
(1)ABR反应器在短HRT及中低温下处理生活污水是可行的,并且对容积负荷的冲击具有较好的适应性。
(2)在水力停留时间12h下,ABR反应器对COD处理效果较好,出水COD<100mg/L,对SS也有一定的去除,去除率在70%以上。
(3)采用ABR-SBR工艺处理生活污水,出水COD和SS达到城镇污水处理厂污染物排放标准(GB118-2002)中一级A标准;出水的氨氮、TN和TP优于GB118-2002的一级B标准。
参考文献:
[1] 范启雄,张金城.ABR-好氧工艺处理生活污水的试验研究[J].中国给水排水,2008,24(9):97-100.
[2] 李清雪,刘书燕,李龙和.低温下厌氧折流板反应器处理生活污水的效能研究[J].中国给水排水,2008,24(23):72-74.
[3] loannis D Manariotis,Sotirios G Grigoropoulos.Low-strengthwastewater treatment using an an aerobic baffled reactorwater [J].Environment Research,2002,74(1):170-176.
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enough, before the treatment and water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance he sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the \"three agriculture\" and \"five water treatment\Board, construction of comprehensive safeguards, \"South Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustment of agricultural planting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, travel living standards, poor farmers in less than complete elimination of 4600 Yuan, 49, 19008. \"Five waters rule\": the County invested 2.169 billion yuan, similar counties line the city's first complete the 42 km of sewage pipe network construction, completion rate ranked first in the city, won the provincial rural sewage treatment work better; key pollution sources such as electroplating, papermaking, chemical industry management through verification and acceptance of the municipal government, the County removed Black and odorous River, River waste, beginning of river ecological restoration effects. \"Three modified a split\" aspects: County total demolition illegal area up 2.759 million square meters, completed City issued annual task of 153%, split against area ranking city second; completed \"three modified\" area 4.846 million square meters, completed City issued annua task of 403%, ranking city third, which village in the a target completed total city ranking first; County Governmentwas named city level \"three modified a split\" work advanced. These achievements are hard won and should be appreciated. However, we are fully aware, the new period, and work in the countryside and the environment facing higher standards and requirements, provincial party Committee offered to high level build a comprehensive well-off society goal requires \"no filth, dirty environment illegal buildings, into a well-off\"; municipal party Committee also proposes to build into the well-off benchmark goals of the city. Compared with the superior claim, \"South Gate of XX beautiful\" goal, my County \"San Nong\" and environment there are a number of weaknesses and gaps, highlighted in the following five aspects: first, agriculture remained \"low\" pattern. \"Low\" is reflected in the quality and low; short, value added of the industry chain is low; 123 fusion yield low employee age, low quality. \"Small\" is reflected in smaller, specialized cooperatives throughout the County there were 3,396, but on the scale of too little. \"San\" is reflected in production, management, services, decentralized, centralized, standardized, brand, information and organizational level is not high. Second, the countryside is still in \"dirty\" phase. \"Dirty\" is dirty of rural sanitation situation has not changed. \"Chaos\" is a village in rural housing construction planning, construction of disorder, no drawings, no construction, no vetting \"four no\" phenomenon, heap lying there. \"Bad\" is the weak rural base, village governance is poor. Thirdly, farmers continued to be \"persistent\" look. \"Old\" is aging, rural labor force accounted for 70% over the age of 50. \"Big\" is that the reform measures ground resistance, such as the transactions of property rights, land replacement; public service supply gap, rural education, health care, pensions and other services can not meet the demand still difficult for poverty alleviation, with emphasis on poverty alleviation and 191. \"Hard\" is a \"peasants, peasants. Four water effects still lacks [4] G V T Gopala Krishna,Pramod Kumar,Pradeep Kumar.Complex wastewater treatment using an anaerobic baffled reactor[J].Environmental Progress,2007,26(4):391-398.
[5] 国家环保总局.水和废水监测分析方法[M].4版.北京:中国环境科学出版社,2002.
ompelling.\" Although the \"five water treatment\" a lot, work very hard, but the flood of scientific enoug\"three agriculture\" and \"five water treatment\Board, construction of comprehensive article. Always tighten the string for food security, \"rice bag\" catch in hand, to hold land in the adjustmetravel nd water quality improvement after the treatment effect is not obvious, county-wide focus on river still largely inferior five water, swimming the River could not be found. Five is \"three to split\" task still lies ahead. Notice of stock there, new construction did not receive timely treatment every year (such as ancestral hall as unauthorised repeated), contrary to the created work is very different from the provincial and municipal standards. Meanwhile, when implementation is not in place, generally only focus on illegal construction demolished, failing that split that is clear, combined demolition, insufficient attention to reconstruction of old residential areas, urban villages, shanty towns and promote poor. o solve these problems, we must enhance the sense of responsibility and urgency, insist on problem-oriented, to take strong measures, efforts to make up the h Gate of XX beautiful\" goal of realizing. II, and precision Shi policy, and manpower playing good \"three agricultural\" work protracted \"three agricultural\" work is do economic social development the work of based, county levels the sector to according to \"based agricultural, and and manpower rural, and development farmers\" of requirements, insisted agricultural rural based status not shake, insisted huinong kulak policy not weakened, insisted reform innovation test not stop, efforts created new era \"three agricultural\" work new situation. (A) to make agriculture more. To establish the concept of agriculture around the people demand, and comprehensively promote the supply side of agriculture structural reform, strive to enhance the quality and efficiency of agriculture and competitiveness. Focus is on doing the four articles. One is the steady increase of grain nting structure in the \"red line.\" Accelerating the construction of grain ribbons, improving agricultural infrastructure, enhance food production capacity, improve the quality of agricultural products, effectively \"steady increase of grain\" and maintain \"tongue.\" Second, industry convergence article. Enhance the level of concentration, intensification of agriculture, creating production, processing, distribution, sales and service in one of the agricultural industrial chain, to break down the value chain, improve added value. Pushing forward \"the Internet + agricultural\" model to improve agricultural production, management, and service level, innovating the mode of e-commerce marketing of agricultural products, solve the difficult problem of sales of agricultural products. Agriculture and tourism, education, culture, health, pension and other deep integration, develop leisure, h, before the treatment asafeguards, \"Soutnt of agricultural pla
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